CC-BYNedelkovski, VladanRadovanović, Milan B.Medić, DraganaStanković, SonjaHulka, IosifTanikić, DejanAntonijević, Milan2025-08-262025-08-2620252227-971710.3390/pr13072240https://repozitorijum.tfbor.bg.ac.rs/handle/123456789/5997This study explores the enhanced photocatalytic performance of boron-doped zinc oxide (ZnO) nanoparticles synthesized via a scalable mechanochemical route. Utilizing X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), the structural and morphological properties of these nanoparticles were assessed. Specifically, nanoparticles with 1 wt%, 2.5 wt%, and 5 wt% boron doping were analyzed after calcination at temperatures of 500 °C, 600 °C, and 700 °C. The obtained results indicate that 1 wt% B-ZnO nanoparticles calcined at 700 °C show superior photocatalytic efficiency of 99.94% methyl orange degradation under UVA light—a significant improvement over undoped ZnO. Furthermore, the study introduces a predictive model using the artificial neural network (ANN) technique, developed in Python, which effectively forecasts photocatalytic performance based on experimental conditions with R2 = 0.9810. This could further enhance wastewater treatment processes, such as heterogeneous photocatalysis, through ANN-guided optimization.enoptimizationdoped ZnOnanoparticlesneural networksphotocatalysisarticle