Al-Sn alloys as composite phase change materials for thermal energy storage: microstructural and thermal characterization

dc.citation.epage12
dc.citation.rankM62
dc.citation.spage11
dc.contributor.authorManasijević, Dragan
dc.contributor.authorBalanović, Ljubiša
dc.contributor.authorMarković, Ivana
dc.contributor.authorGorgievski, Milan
dc.contributor.authorStamenković, Uroš
dc.contributor.authorKovacević, Avram
dc.date.accessioned2025-06-26T07:48:17Z
dc.date.available2025-06-26T07:48:17Z
dc.date.issued2025
dc.description.abstractAl–Sn alloys are well known for their excellent resistance to wear and corrosion, as well as their solid mechanical performance, making them popular choices for bearing applications [1,2]. More recently, however, they have attracted attention as potential composite phase change materials (C-PCMs) for thermal energy storage (TES) systems. To determine their suitability for such applications, a thorough investigation of their thermal characteristics is essential. In this study, Al–Sn alloys containing 11.7, 22.4, 32.8, 41.1, and 53.4 atomic percent Sn were prepared by melting high-purity metals. Continuous stirring of the melt was employed to prevent segregation, followed by casting into stainless steel molds. The resulting ingots displayed uniform microstructures, free of cracks and pores. Thermal diffusivity of the solid Al–Sn samples was measured between 25°C and 150°C using the light flash method. Density at room temperature was determined via the Archimedes principle, while specific heat capacities across different temperatures were calculated using the CALPHAD (Calculation of Phase Diagrams) approach. Thermal conductivity values were then derived using an appropriate conversion relationship. Additionally, phase transition temperatures and the associated thermal effects were analyzed by differential scanning calorimetry (DSC). The study mapped how thermal conductivity changes with both alloy composition and temperature, and also assessed how latent heat of fusion varies across the compositions. Microstructural and phase composition analyses were performed using scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS). The findings offer valuable insights into the thermal behavior and microstructural characteristics of Al–Sn alloys, contributing to the development of advanced PCMs for thermal energy storage applications.
dc.identifier.isbn978-86-81656-84-6
dc.identifier.urihttps://repozitorijum.tfbor.bg.ac.rs/handle/123456789/5980
dc.language.isoen
dc.publisherFakultet Tehničkih nauka, Kosovska Mitrovica
dc.rights.licenseCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.sourceZbornik izvoda radova- Dvanaesti simpozijum o termodinamici i faznim dijagramima sa međunarodnim učešćem, Kosovska Mitrovica, 20-21. jun 2025. god.
dc.titleAl-Sn alloys as composite phase change materials for thermal energy storage: microstructural and thermal characterization
dc.typeconferenceObject
dc.type.versionpublishedVersion

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