Kinetic and DTA-TGA analysis of Cu2+ biosorption on hazelnut shells
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Date
2025
Authors
Gorgievski, Milan
Marković, Miljan
Štrbać, Nada
Manasijević, Dragan
Grekulović, Vesna
Jovanović, Dalibor
Marković, Marina
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Fakultet Tehničkih nauka, Kosovska Mitrovica
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Zbornik izvoda radova- Dvanaesti simpozijum o termodinamici i faznim dijagramima sa međunarodnim učešćem, Kosovska Mitrovica, 20-21. jun 2025. god.
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Abstract
Biosorption can be defined as the ability of biomaterials to accumulate and concentrate heavy metals from even the most dilute aqueous solutions. The biosorption process involves a solid phase (biological material) and a liquid phase (solvent, usually water) containing the dissolved metal. [1]. In this work, hazelnut shells were used as biosorbents for the biosorption of Cu2+ ions from synthetic solutions. This paper presents the results of kinetic and DTA-TGA analysis of the biosorption of Cu2+ ions on hazelnut shells. A pseudo-first order kinetic model, a pseudo-second order kinetic model, an intraparticle diffusion kinetic model and an Elovich kinetic model were used to describe the kinetics of biosorption of Cu2+ ions with hazelnut shells. The change in the adsorption capacity of copper ions with time was determined by contacting a series of solutions of copper ions with an initial concentration of 0.2 g dm-3 with 0.5 g of the sample for different contact times. Biosorption was terminated after 90 minutes, assuming that this time was long enough to establish equilibrium in the system [2]. It can be seen from Fig. 1a that at the beginning of the process (in the first 10 minutes) the adsorption capacity increases sharply with the contact time. The sudden increase in capacity in the first 10 minutes of the process is due to the large number of active sites available on the surface of the adsorbent. Thereafter, until the end of the experiment, a slight increase in adsorption capacity can be observed, which is due to the decrease in available active sites and the decrease in the concentration of copper ions in the solution [3]. The pseudo-second order kinetic model, with the correlation coefficient R2 = 0.961, showed the best agreement with the experimental data. Based on this model it can be concluded that chemisorption is a possible binding mechanism of copper ions on the surface of hazelnut shells [4].
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Scopus
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ISBN
978-86-81656-84-6
License
CC-BY